When referring to the Spectral Atlas, please cite our publication:
Keller-Rudek, H., Moortgat, G. K., Sander, R., and Sörensen,
R.: The MPI-Mainz UV/VIS spectral atlas of gaseous molecules of
atmospheric interest, Earth Syst. Sci. Data, 5, 365–373, (2013),
DOI: 10.5194/essd-5-365-2013
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DATAFILE: | Cl2O6_GoodeveRichardson(1937)_273-276.5K_200-350nm.txt |
NAME: | dichlorine hexoxide, chloryl chlorate |
FORMULA: | Cl2O6 |
AUTHOR(YEAR): | GoodeveRichardson(1937) |
T: | 273-276.5K |
λ: | 200-350nm |
BIBLIOGRAPHY: |
C.F. Goodeve and F.D. Richardson, "The absorption spectrum of chlorine trioxide and chlorine hexoxide",
Trans. Faraday Soc. 33, 453-457 (1937);
DOI: 10.1039/TF9373300453
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COMMENTS: | Structure: O3ClOClO2
Graphical interpolation of the absorption curve shown in Fig. 1 by
R.D. Hudson, "Chlorofluoromethanes and the stratosphere", NASA Reference Publication 1010 (1977), pp. 33 and 36
The spectrum has originally been attributed to ClO3
Because of its shape and in spite of the low absorption cross sections, the spectrum has been attributed to Cl2O6 by
M.I. Lopez and J.E. Sicre, "Physicochemical properties of chlorine oxides. 1. Composition, ultraviolet spectrum, and kinetics of the thermolysis of gaseous dichlorine hexoxide, J. Phys. Chem. 94, 3860-3863 (1990); DOI: 10.1021/j100372a094 |
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